Publications

Synthesis of bulk Nd₁₋ₓSrₓNiO₂ and Nd₁₋ₓSrₓNiO₃ improved with the A-HSO at Argonne National Lab

Resulting from the recent observation of superconductivity in Nd₁₋ₓSrₓNiO₂ the interest in the infinite-layer RNiO2 (R = La, Nd) compounds revived. Since experimental reports into RNiO2 compounds are quite limited, Nd₁₋ₓSrₓNiO₂ and its precursor Nd₁₋ₓSrₓNiO₃ were synthesized and characterized at Argonne National Lab. Experience shows, that introducing Sr2+ into the RNiO₂ structure as a dopant requires quite high temperatures and oxygen pressures. For experimental challenges like this one our A‑HSO furnace was developed in cooperation with John F. Mitchell. For the different experimental approaches the A‑HSO was used for the final treatment of the priorly received material at 1000 °C and 150-160 bar of oxygen pressure. This high pressure annealing technique was decisive to get well crystallized and pure Nd₁₋ₓSrₓNiO₃. The subsequently obtained Nd₁₋ₓSrₓNiO₂ was characterized by its electrical transport properties and neutron diffraction at different temperatures.. We're excited to learn for which other interesting materials the A‑HSO will be of use.

https://journals.aps.org/prmaterials/abstract/10.1103/PhysRevMaterials.4.084409

2020_Mitchell_Neodymstrontiumnickelates.png

Posted in Publications on Feb 21, 2025.