The crystal growth group from Max-Planck-Institute for Chemical Physics of Solids in Dresden succeeded recently in the synthesis of barium-substituted strontium ruthernates using a ScIDre high-pressure floating zone furnace HKZ.

High quality single crystals of Ba-substituted ruthenate Sr2-xBaxRuO4, the "large volume variant" of the unconventional superconductor Sr2RuO4, were grown at the Max-Planck-Institute for Chemical Physics of Solids in Dresden for x-values up to 0.4. The heavy evaporation of RuO2 during the growth procedure could be handled by  Ru-excess y in the feed rod which acts as self-flux and gas pressures up to 150 bar using a mixture of argon and O2 with a ratio of 9:1 with a flowing rate of 1 l/min.

Li et al. 2015